膜科学与技术

ATRP表面接枝在功能膜制备中的应用

作者：杨万泰，李春燕

单位：北京化工大学材料科学与工程学院化工资源有效利用国家重点实验室

关键词：原子转移自由基聚合、表面引发、引发剂固定、功能膜、综述

出版年,卷(期):页码： 2011,31(3):110-117

摘要：

ATRP表面引发接枝聚合是功能膜制备中一个重要而有效的方法。近年来，随着原子转移自由基聚合（ATRP）研究的快速发展，将ATRP应用于功能膜制备的研究已取得了显著的进展。本文详细介绍了在膜表面固定ATRP引发剂的方法及将ATRP表面接枝法应用于制备抗污染能力强,抗菌性好,环境响应迅速等多种功能性膜方面的研究进展情况。

Recent progress in atom transfer radical polymerization (ATRP), in particular surface-initiated ATRP, has provided an important, effective and unique means for the design and preparing functional membrane. This review summarizes such recent research activities. The three main strategies of immobilization ATRP initiators on the different membrane surface are described in detail. The application suited particularly of highly robust and versatile ATRP technique in the preparation of functional membrane, including antifouling, antibacterial, stimuli responsive membrane. The research activities in the last decade indicate that surface-initiated ATRP has become an essential tool for the design and synthesis of advanced, noble and novel membrane.

杨万泰，男，教授

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