表面粗糙度对输液排气膜疏水性能的影响
作者:王?洪1,王金成1,吕永存2,辛公芬2,朱景元2
单位: 1东华大学纺织面料技术教育部重点实验室,上海201620) 2上海振浦医疗设备有限公司,上海200126
关键词: 表面粗糙度;接触角;疏水;分形维数;Wenzel模型
出版年,卷(期):页码: 2016,36(2):70-75

摘要:
 采用浸渍法在输液排气膜坯布表面引入粗糙结构,以提高排气膜的疏水性。用红外光谱表征处理前后样品表面的化学结构变化,用接触角表征坯布表面疏水性,并测试了处理前后坯布孔径及透气性变化。并用分形理论对处理前后坯布表面的粗糙度进行表征,同时对分形结构的Wenzel模型进行了验证。结果表明,通过在坯布表面引入粗糙PVDF(聚偏氟乙烯)颗粒,对进一步提高坯布的拒水性是可行的。
 In this paper, in order to improve the water repellency of exhaust membrane for intravenous transfusion, rough surface was introduced on to the membrane by dipping method. The wettability of the exhaust membrane was characterized by contact angles. Chemical composition changes of samples before and after treatment were measured by the infrared spectrum, and pore size and permeability of the exhaust membrane before and after finishing were analyzed. The values of the fractal dimension describing roughness of untreated and treated membranes were calculated. And Wenzel model of fractal structure was verified. The results showed that it is feasible to further improve the water repellency of the membrane by introducing PVDF particles.

参考文献:
 [1] Wenzel R N. Resistance of solid surface to wetting by water [J].Ind Eng Chem. 1936,28(8):988-994.     
[2] GB/T 5453-1997,纺织品 织物透气性的测定[S].          
[3] 刘培生. 多孔材料孔径及孔径分布的测定方法[J].钛工业进展,2006,23(2):29-34.     
[4] ASTMD5725-1999,Surface wettability and absorbency of sheeted materials using an automated contact angle tester [S].                                
[5] Nishino T,Meguro M,Nakamae K,et al. The lowest surface free energy based on -CF3 alignment[J]. Langmuir,1999,15(13):4321-4323.
[6] 冯计民. 红外光谱在微量物证分析中的应用[M]. 北京:化学工业出版社,2010:95,175.
[7] Shibuichi S,Onda T,Satoh N,et al. Super water-repellent surfaces resulting from fractal structure[J]. J Phys Chem,1996,100(50) :19512-19517.
[8] 洪碧圆. 超疏水表面的制备、性质和应用[D]. 浙江:浙江大学,2012:24.
[9] Vicsek T. Fractal growth phenomena[M]. Singapore:World Scientific Publishing,1989:48-65.
[10] Fang W J,Mayama H,Tsujii K. Spontaneous formation of fractal structures on triglyceride surfaces with reference to their super water-repellent properties [J]. J Phys Chem B,2007,111(3):564-571.
 

服务与反馈:
文章下载】【加入收藏

《膜科学与技术》编辑部 地址:北京市朝阳区北三环东路19号蓝星大厦 邮政编码:100029 电话:010-64426130/64433466 传真:010-80485372邮箱:mkxyjs@163.com

京公网安备11011302000819号