膜分离技术在乳品加工行业中的应用
作者:笪晓薇,齐婷,柯威,陈献富,范益群
单位: 1. 南京膜材料产业技术研究院有限公司,南京 211800; 2. 南京工业大学 化工学院,材料化学工程国家重点实验室,南京 210009
关键词: 膜分离;微滤;超滤;纳滤;乳品加工
出版年,卷(期):页码: 2022,42(4):157-162

摘要:
 膜分离技术在乳品加工行业中占据着极其重要的地位,可基于膜孔径筛分作用及电荷效应,实现不同功能目标产物的高效分离。本文介绍了膜分离技术的过程及机理,并对不同类型的膜在乳品加工行业中的应用进行了分析讨论,重点阐述了乳品工业各环节中膜技术应用的难点及其相关研究成果,主要包括乳品除菌、乳品浓缩、蛋白分离、乳糖脱除及加工废水处理。最后基于目前所采用的膜材料及工艺,指出了膜技术处理乳制品未来的研究方向,为膜分离技术在乳品加工行业中的应用提供指导。
  Membrane technology exhibits a wide range of applications in dairy processing. The highly efficient separation of target products with different properties could be achieved by membranes via sieving effect and Donnan effect. This review focuses on the principle of membrane separation technology and the application in dairy industry. Then the main problem for application of membrane technology in dairy industry and research progress of dairy production by membrane technology are mainly emphasized, mainly including degerming, concentration, protein fractionation, lactose fractionation and dairy wastewater treatment. Finally, according to the membrane material and the process, the future development prospect was also prospected. 
笪晓薇(1988-),女,江苏句容,中级工程师,博士,陶瓷膜材料的制备与应用

参考文献:
 [1] Gebreyowhans S, Lu J, Zhang S, et al. Dietary enrichment of milk and dairy products with n-3 fatty acids: A review[J]. Int Dairy J, 2019, 97: 158-166.
[2] Lawrence M, Polukis S, Barnard A M, et al. Evaluating the effects of Lactobacillus animalis and Propionibacterium freudenreichii on performance and rumen and fecal measures in lactating dairy cows[J]. J Dairy Sci, 2021, 104(4): 4119-4133.
[3] Lu H B, Wang Y C, Bovenhuis H. Phenotypic and genetic effects of season on milk production traits in dairy cattle in the Netherlands[J]. J Dairy Sci, 2021, 104(4): 4486-4497.
[4] Carter B, DiMarzo L, Pranata J, et al. Determination of the efficiency of removal of whey protein from sweet whey with ceramic microfiltration membranes[J]. J Dairy Sci, 2021, 104(7): 7534-7543.
[5] Doan N T T, Lai Q D. Ultrafiltration for recovery of rice protein: Fouling analysis and technical assessment[J]. Innov Food Sci Emerg, 2021, 70: 102692.
[6] Marchetti P, Solomon M F J, Szekely G, et al. Molecular separation with organic solvent nanofiltration: A critical review[J]. Chem Rev, 2014, 114(21): 10735-10806.
[7] Del Re G, Di Giacomo G, Aloisio L, et al. RO treatment of waste waters from dairy industry[J]. Desalination, 1998, 119(1): 205-206.
[8] Pouliot Y. Membrane processes in dairy technology - From a simple idea to worldwide panacea[J]. Int Dairy J, 2008, 18(7): 735-740.
[9] Wang M, Cao C, Wang Y, et al. Comparison of bovine milk fat globule membrane protein retention by different ultrafiltration membranes using a label-free proteomic approach[J]. LWT, 2021, 144: 111219.
[10] Holm S. Method for producing milk with a lowered bacterial content:US, US4876100A[P]. 1989-10-24.
[11] Saboya L V, Maubois J L. Current developments of microfiltration technology in the dairy industry[J]. Lait, 2000, 80(6): 541-553.
[12] Maubois J L. Membrane microfiltration: a tool for a new approach in dairy technology[J]. Australian Journal of Dairy Technology, 2002, 57(2): 92-96.
[13] 吕加平, 丁玉振, 于景华, 等. 牛奶微滤除菌技术研究[J]. 中国乳品工业, 2005, 33: 15-18.
[14] Graf B, Kohler E, Rosenberger M, et al. Shelf-stable milk produced by microfiltration and microwave heating: Effects of processing and storage[J]. J Food Eng, 2021, 311: 110734.
[15] Pinto M S, Pires A C S, Sant’Ana H M P, et al. Influence of multilayer packaging and microfiltration process on milk shelf life[J]. Food Packaging Shelf, 2014, 1(2): 151-159.
[16] 王志高,范从军,彭文博,等. 一种卫生级陶瓷膜组件:中国,CN204034571U2004[P]. 2004-10-24.
[17] Hartinger M, Heidebrecht H J, Schiffer S, et al. Milk protein fractionation by means of spiral-wound microfiltration membranes: Effect of the pressure adjustment mode and temperature on flux and protein permeation[J]. Foods, 2019, 8(6): 17.
[18] Wang D, Fritsch J, Moraru C I. Shelf life and quality of skim milk processed by cold microfiltration with 1.4-μm pore size membrane, with or without heat treatment[J]. J Dairy Sci, 2019, 102(10): 8798-8806.
[19] Elwell M W, Barbano D M. Use of microfiltration to improve fluid milk quality[J]. J Dairy Sci, 2006, 89: E20-E30.
[20] 徐姝,刘大松,李志宾,等. 巴氏杀菌、微滤及紫外处理对羊乳中菌落数与活性蛋白的影响[J]. 食品与发酵工业, 2021, 47(15): 150-156.
[21] Zhang W, Liu Y, Li Z, et al. Effects of microfiltration combined with ultrasonication on shelf life and bioactive protein of skim milk[J]. Ultrason Sonochem, 2021, 77: 105668.
[22] 吴士业,罗惠波,刘达玉. 超滤技术开发低乳糖乳粉的研究[J]. 四川轻化工学院学报, 2004, 17(1): 372-382.
[23] 刘大松,余韵,李珺珂,等. 脱钙预处理对提高浓缩乳蛋白溶解性的影响[J]. 食品与发酵工业, 2017, 43(5): 80-92.
[24] Ng K S Y, Haribabu M, Harvie D J E, et al. Mechanisms of flux decline in skim milk ultrafiltration: A review[J]. J Membr Sci, 2017, 523: 144-162.
[25] Steinhauer T, Marx M, Bogendörfer K, et al. Membrane fouling during ultra- and microfiltration of whey and whey proteins at different environmental conditions: The role of aggregated whey proteins as fouling initiators[J]. J Membr Sci, 2015, 489: 20-27.
[26] Konrad G, Kleinschmidt T, Faber W. Ultrafiltration flux of acid whey obtained by lactic acid fermentation[J]. Int Dairy J, 2012, 22(1): 73-77.
[27] 景文珩,何华婷,邢卫红,等. 一种抗蛋白吸附陶瓷复合膜的制备方法:中国,CN102059059A[P]. 2011-05-18.
[28] Hilal N, Ogunbiyi O O, Miles N J, et al. Methods employed for control of fouling in MF and UF membranes: A comprehensive review[J]. Sep Sci Technol, 2005, 40(10): 1957-2005.
[29] Sarkar A, Moulik S, Sarkar D, et al. Performance characterization and CFD analysis of a novel shear enhanced membrane module in ultrafiltration of Bovine Serum Albumin (BSA)[J]. Desalination, 2012, 292: 53-63.
[30] Luo J, Ding L, Wan Y, et al. Threshold flux for shear-enhanced nanofiltration: Experimental observation in dairy wastewater treatment[J]. J Membr Sci, 2012, 409/410: 276-284.
[31] Carter B G, Cheng N, Kapoor R, et al. Invited review: Microfiltration-derived casein and whey proteins from milk[J]. J Dairy Sci, 2021, 104(3): 2465-2479.
[32] Walstra P, Geurts T J, Noomen A, et al. Dairy technology: Principles of milk properties and processes[M]. New York: Marcel Dekker Inc, 1999.
[33] 王志高,邢卫红,徐南平. 陶瓷膜过滤牛初乳过程的污染阻力分析[J]. 膜科学与技术, 2004, 24(1): 28-37.
[34] Schiffer S, Matyssek A, Hartinger M, et al. Effects of selective layer properties of ceramic multi-channel microfiltration membranes on the milk protein fractionation[J]. Sep Purif Technol, 2021, 259: 118050
[35] Zydney A L. Protein separations using membrane filtration: New opportunities for whey fractionation[J]. Int Dairy J, 1998, 8(3): 243-250.
[36] Akpinar-Bayizit A, Ozcan T, Yilmaz-Ersan L. Membrane processes in production of functional whey components[J]. Mljekarstvo, 2009, 59(4): 282-288.
[37] 孙颜君,郭本恒,莫蓓红,等. α-乳白蛋白粉和/或β-乳球蛋白粉的制备方法及产品:中国,CN104256053A[P]. 2017-06-20.
[38] 孙颜君,莫蓓红,郑远荣,等. 膜分离法制备高α-乳白蛋白质量分数的乳清蛋白浓缩物80[J]. 中国乳品工业, 2014, 43(1): 11-15.
[39] Costa A, Lopez-Villalobos N, Sneddon N W, et al. Invited review: Milk lactose—Current status and future challenges in dairy cattle[J]. J Dairy Sci, 2019, 102(7): 5883-5898.
[40] Genvrain S A. Delactosed milk prepn - by ultra filtration of milk followed by inverse osmosis to separate lactose:France, FR2125137A1[P]. 1972-09-29.
[41] 刘金杰,王世宾. 创新改变生活:芬兰无乳糖牛奶专利技术[C] //中国乳制品工业协会第十二次年会论文集. 中国乳制品工业协会,2006:245-246.
[42] 方雅悯. 一种同时生产低钠无糖牛奶和乳糖的方法:中国, CN1784998A[P]. 2006-06-14.
[43] 刘选东. 基于膜分离技术的低乳糖牛乳制备[D]. 安徽:安徽农业大学,2016.
[44] 杨宝雨. 基于陶瓷膜技术的羊乳膜分离工艺研究[D]. 山东:烟台大学,2019. 
[45] Balannec B, Gesan-Guiziou G, Chaufer B, et al. Treatment of dairy process waters by membrane operations for water reuse and milk constituents concentration[J]. Desalination, 2002, 147(1-3): 89-94.
[46] Sharma U, Shalini S, Basu S, et al. Active layer modification of commercial nanofiltration membrane using CuBTC/PVA matrix for improved surface and separation characteristics[J]. J Appl Polym Sci, 2021, 138(21): 1-12.
[47] Luo J, Ding L, Qi B, et al. A two-stage ultrafiltration and nanofiltration process for recycling dairy wastewater[J]. Bioresour Technol, 2011, 102(16): 7437-7442.
[48] Brião V B, Vieira Salla A C, Miorando T, et al. Water recovery from dairy rinse water by reverse osmosis: Giving value to water and milk solids[J]. Resour Conserv Recy, 2019, 140: 313-323.

服务与反馈:
文章下载】【加入收藏

《膜科学与技术》编辑部 地址:北京市朝阳区北三环东路19号蓝星大厦 邮政编码:100029 电话:010-64426130/64433466 传真:010-80485372邮箱:mkxyjs@163.com

京公网安备11011302000819号